Consider the voltaic cell diagram: Sn(s) | Sn2⁺(aq) || Ag⁺ (aq) | Ag (s) What is the standard cell potential, E°cell, (in V) for this voltaic cell? Hint: Refer to the table of standard reduction potentials provided. Half Reaction E° red (V) Ag+ (aq) + e– → Ag (s) +0.80 Fe3+ (aq) + e– → Fe2+ (aq) +0.77 Cu2+ (aq) + 2 e– → Cu (s) +0.34 Sn4+ (aq) + 2 e– → Sn2+ (aq) +0.15 2H+ (aq) + 2 e– → H2 (g) 0.00 Pb2+ (aq) + 2 e – → Pb (s) –0.13 Sn2+ (aq) + 2 e– → Sn (s) –0.14 Ni2+ (aq) + 2 e – → Ni (s) –0.28 Cd2+ (aq) + 2 e – → Cd (s) –0.40 Fe2+ (aq) + 2 e – → Fe (s) –0.44 Cr3+ (aq) + 3 e– → Cr (s) –0.74 Zn2+ (aq) + 2 e – → Zn (s) –0.76 Al3+ (aq) + 3 e– → Al (s) –1.66
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The combustion of ammonia proceeds by the reaction …
The combustion of ammonia proceeds by the reaction 4 NH3 + 7 O2 → 4 NO2 + 6 H2O When the rate of appearance of H2O is 1.10 Ms-1, the rate of disappearance of O2 is Ms-1
A sample of sodium bicarbonate, NaHCO3, is placed in a clos…
A sample of sodium bicarbonate, NaHCO3, is placed in a closed 1.0 L vessel at 398 K and allowed to decompose unil it reaches equilibrium according to the following equation: 2 NaHCO3 (s) ⇌ Na2CO3(s) + H2O (g) + CO (g) Kp = 0.450 What is the partial pressure of CO (in atm) at equilibrium?
Phophorous-32 decays by beta emission to form sulfur-32. …
Phophorous-32 decays by beta emission to form sulfur-32. (In case the picture does not show: The picture indicated that 24 P-32 decayed to 3 P-32 in 9min. ) What is the decay constant, k, for P-32?
The following hypothetical reaction is zero order in A, seco…
The following hypothetical reaction is zero order in A, second order in B, and first order in C: A + B + C → products What is the correct rate law and the overall order of this reaction?
Given the Kc value for the following reaction at a particula…
Given the Kc value for the following reaction at a particular temperature: SO2 (g) + ½ O2 (g) ⇋ SO3 (g) Kc = 9.75 What is the value of Kc for the new equilibrium below at the same temperature? 2 SO3 (g) ⇋ 2 SO2 (g) + O2 (g)
Consider the following reaction: BrO3⎻ (aq) + 5 Br⎻(aq)…
Consider the following reaction: BrO3⎻ (aq) + 5 Br⎻(aq) + 6 H+(aq) → Br2(aq) + H2O(l) This reaction has the rate law:
Given the equilibrium constant, Kc = 3.0 x 103 for the follo…
Given the equilibrium constant, Kc = 3.0 x 103 for the following reaction: 2 KCl (s) + 3 O2(g) ⇌ 2 KClO3(s) What is the concentration of O2 (in M) at equilibrium?
The rate constant for a particular second order reaction is…
The rate constant for a particular second order reaction is k = 0.0152 M−1 s −1 at 35°C. If the initial concentration of reactant is 3.25 M, what is the concentration after 4 minutes? Hint: Make sure all units agree!
Which of the following authors is most associated with Gothi…
Which of the following authors is most associated with Gothic literature in early America?