Author: Anonymous

A buffer with highest capacity can be achieved when pH is equal to the pKa of its acid component. Consider a buffer solution prepared by adding 0.100 M HCl to [V1] mL of 0.020 M ammonia. At which volume of hydrochloric acid added will the buffer subsequently achieve its highest buffer capacity? Express your answer to 1 decimal place.

The following scenes (1, 2, and 3) represent solutions of silver (black) and chloride (green) ions that are above solid silver chloride AgCl. (The solid, other ions, and water are not shown) a. Which scene best represents the solution in equilibrium with the solid in water? [A] b. In which, if any, other scene(s) will additional solid form? [B] c. Once the equilibrium has established in all scenes if applicable, how will addition HCl (aq) affect the mass of solid present in any scene? [C]    

Classify each of the following as a Lewis acid or a Lewis base. H– : [h-] Br– : [br] Fe3+ : [fe] NH3 : [nh3] BH3 : [bh3]

A buffer with highest capacity can be achieved when pH is equal to the pKa of its acid component. A buffer solution is prepared by adding 0.050 M NaOH to [V1] mL of 0.010 M nitrous acid, HNO2. At which volume of sodium hydroxide added will the buffer subsequently achieve its highest buffer capacity? Input your answer to 1 decimal place.

Consider the crystal field splitting pattern for octahedral complexes to answer the following questions. A. How many electrons are unpaired in a d6 high-spin complex? [A] B. How many electrons are unpaired in a d4 low-spin complex? [B]

An unknown metal M that has Ksp of MS in water is [Ksp] x 10−22 and Kf of M(OH)42− is [Kf] x 1014. Calculate the molar solubility of MS in 2.0 M NaOH. Multiply your answer by 104 and express the final answer to 2 decimal places.  

The de Broglie equation predicts that the wavelength (in m) of a proton moving at 1000. m/s is ________. (mass of a proton = 1.673 × 10–24 g)

Calculate the pH of a solution containing [c]M pyridine, C5H5N. (Kb = 1.7×10-9) Express your answer to two decimal places.

 PbCl2 has a Ksp of 1.1×10−5. Solutions of lead (II) nitrate and aluminum chloride are mixed, forming a solution containing 0.020 M Pb(NO3)2 and 0.010 M AlCl3. What can be said of this solution?

The following anions can be separated by precipitation as lead salts: OH-, I–, CrO42–, AsO43- . If Pb2+ is added to a solution containing the four anions (each anion at a concentration of 0.10 M) in what order will they precipitate?   First, [I] Second, [II] Third, [III] Fourth, [IV]   Compound Ksp PbCrO4= 1.8 x 10–14 Pb3(AsO4)2= 4.1 x 10–36 Pb(OH)2= 2.8 x 10–16 PbI2= 8.7 x 10–9